Physical function

Like a normal diode, an LED consists of a chip of semiconducting material impregnated, or doped, with impurities to create a p-n junction. As in other diodes, current flows easily from the p-side, or cathode, to the n-side, or anode, but not in the reverse direction. Charge-carriers electrons and electron holes flow into the junction from electrodes with different voltages. When an electron meets a hole, it falls into a lower energy level, and releases energy in the form of a photon.

The wavelength of the light emitted, and therefore its colour, depends on the band gap energy of the materials forming the p-n junction. In silicon or germanium diodes, the electrons and holes recombine by a non-radiative transition which produces no optical emission, because these are indirect band gap materials. The materials used for an LED have a direct band gap with energies corresponding to near-infrared, visible or near-ultraviolet light.

LED development began with infrared and red devices made with gallium arsenide. Advances in materials science have made possible the production of devices with ever-shorter wavelengths, producing light in a variety of colors.

LEDs are usually built on an n-type substrate, with electrode attached to the p-type layer deposited on its surface. P-type substrates, while less common, occur as well. Many commercial LEDs, especially GaN/InGaN, also use sapphire substrate. Substrates that are transparent to the emitted wavelength, and backed by a reflective layer, increase the LED efficiency. The refractive index of the package material should match the index of the semiconductor, otherwise the produced light gets partially reflected back into the semiconductor, where it gets absorbed and turns into additional heat lowering the efficiency. In 2007 experiments tried to avoid multiple internal reflection by roughening the chip. Again at the surface from the package to a low refractive index medium like a glass fiber or air total internal reflection is avoided by using a sphere shaped package, with the diode in the center, so that the light rays hit the surface quite perpendicular, and anti-reflection coating may be added. The package may be cheap plastic, which may be colored, but this is only for cosmetic reasons or to improve the contrast ratio; the color of the packaging does not substantially affect the color of the light emitted.

White LEDs

Blue LEDs can be added to existing red and green LEDs to produce the impression of white light, though white LEDs today rarely use this principle. Most "white" LEDs in production today are based on an InGaN-GaN structure, and emit blue light of wavelengths between 450 nm C 470 nm blue GaN. These GaN-based, InGaN-active-layer LEDs are covered by a yellowish phosphor coating usually made of cerium-doped yttrium aluminum garnet (Ce3+:YAG) crystals which have been powdered and bound in a type of viscous adhesive. The LED chip emits blue light, part of which is efficiently converted to a broad spectrum centered at about 580 nm (yellow) by the Ce3+:YAG. The single crystal form of Ce3+:YAG is actually considered a scintillator rather than a phosphor. Since yellow light stimulates the red and green receptors of the eye, the resulting mix of blue and yellow light gives the appearance of white, the resulting shade often called "lunar white". This approach was developed by Nichia and was used by them from 1996 for manufacturing of white LEDs.

The pale yellow emission of the Ce3+:YAG can be tuned by substituting the cerium with other rare earth elements such as terbium and gadolinium and can even be further adjusted by substituting some or all of the aluminum in the YAG with gallium. Due to the spectral characteristics of the diode, the red and green colors of objects in its blue yellow light are not as vivid as in broad-spectrum light. Manufacturing variations and varying thicknesses in the phosphor make the LEDs produce light with different color temperatures, from warm yellowish to cold bluish; the LEDs have to be sorted during manufacture by their actual characteristics. Philips Lumileds patented conformal coating process addresses the issue of varying phosphor thickness, giving the white LEDs a more consistent spectrum of white light.

Spectrum of a "white" LED clearly showing blue light which is directly emitted by the GaN-based LED (peak at about 465 nanometers) and the more broadband stokes shifted light emitted by the Ce3+:YAG phosphor which extends from around 500 to 700 nanometers.White LEDs can also be made by coating near ultraviolet (NUV) emitting LEDs with a mixture of high efficiency europium-based red and blue emitting phosphors plus green emitting copper and aluminum doped zinc sulfide (ZnS:Cu, Al). This is a method analogous to the way fluorescent lamps work. However the ultraviolet light causes photodegradation to the epoxy resin and many other materials used in LED packaging, causing manufacturing challenges and shorter lifetimes. This method is less efficient than the blue LED with YAG:Ce phosphor, as the Stokes shift is larger and more energy is therefore converted to heat, but yields light with better spectral characteristics, which render color better. Due to the higher radiative output of the ultraviolet LEDs than of the blue ones, both approaches offer comparable brightness.

The newest method used to produce white light LEDs uses no phosphors at all and is based on homoepitaxially grown zinc selenide (ZnSe) on a ZnSe substrate which simultaneously emits blue light from its active region and yellow light from the substrate.

A new technique developed by Michael Bowers, a graduate student at Vanderbilt University in Nashville, involves coating a blue LED with quantum dots that glow white in response to the blue light from the LED. This technique produces a warm, yellowish-white light similar to that produced by incandescent bulbs.